There are two main types of spray foam to consider: open-cell and closed-cell. Open-cell spray foam has a lower R-value per inch and because of this, typically a lower price tag. The soft, low-density material is used for interior applications. Its high permeability allows for moisture to pass through, which contributes to bi-directional drying of the assembly, but it may not be ideal for all applications or climates.
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Spray foam is a very specialized packing material, often required for use in shipping valuable fragile items. Engineered packaging principles are designed to protect sculptures, vases, large fossils, lamp bases, busts, computers, furniture, chandeliers and other objects of unusual shape. By virtue of the liquid foam expanding by up to 30-60 times the volume of its liquid state, it efficiently protects almost any size, form and weight.
A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.