Acrylic coatings are typically applied in two coats, with the second running perpendicular to the first. 1 gallon per 100 square feet is a good estimate for these coatings, as they do not need to be applied nearly as thick as many other coatings. These coatings can be sprayed or roll-applied. Acrylic coatings generally require a re-coat within 2-3 years of application. http://www.youtube.com/watch?feature=youtube_gdata&v=ggLAUsiuI_o
There are two main types of spray foam to consider: open-cell and closed-cell. Open-cell spray foam has a lower R-value per inch and because of this, typically a lower price tag. The soft, low-density material is used for interior applications. Its high permeability allows for moisture to pass through, which contributes to bi-directional drying of the assembly, but it may not be ideal for all applications or climates.
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A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.