In the early days of insulating attics, people believed the insulation was a heat source. That’s not the case, as the insulation is actually a barrier between two areas of different temperatures. As for the “hot roof” theory, the unvented attic system could make the temperature of the roof go up a little, but this increase won’t cause damage to your shingles.
once the foam is installed correctly, it is a inert plastic not much different than the foam cushions you sit on. there is not a health rick unless you have off ratio uncured foam that has not mixed properly. the foam is absolutely a health risk in its raw forms before it is mixed and cured. You should not be in the building without proper respirators and eye protection. The spray foam industry should be controlled and regulated by the same standards, testing and inspections that framing ,electrical and plumbing are. until that happens then you will have idiots with spray rigs ruining peoples homes and ruining the market for honest foam contractors that know how to price a job fairly and complete it correctly.
Sporadic cases of hypersensitivity pneumonitis (HP) have also been reported in workers exposed to isocyanates. The symptoms may seem like the flu, with fever, muscle aches, and headaches. Other symptoms may include a dry cough, chest tightness, and difficult breathing. Individuals with chronic HP often experience progressively more difficult breathing, fatigue, and weight loss. Individuals with acute HP typically develop symptoms 4–6 hours after exposure.[4]

This is in great contrast to my friend's experience. Her attic spaces were sprayed and the foam is actually pretty, and I was in her attic 6-7 days after it was sprayed and could hardly smell anything when I stuck my face up to the foam. And she did not have to clean up one speck of dust during or after the spraying. I got the name/number of the guy from her who managed her attic project, but between the time he did my house and the time he did her house, he was let go from the company who did her attic and hired by another company. He assured me everything would be the same, etc., etc., and I had no reason to believe anything had changed, but the sprayers who did my house later admitted they had never sprayed an attic before and I also found out that the foam used in my attic was from a different manufacturer. Neither my friend nor I had any idea this guy was with different company then, until the week after they filled my attic with off ratio foam, and my home with toxic vapors.    https://www.youtube.com/watch?v=ggLAUsiuI_o&hc_location=ufi

Check with the coating manufacturer who may be able to suggest applicators who have used their products and have familiarity with the application. Another option would be to interview contractors and ask specific questions about their proven ability to install roof coatings. Contractors affiliated with the National Roofing Contractors Association (NRCA) or local roofing contractor trade associations typically are more knowledgeable. Consult those groups’ websites for contractors. 

I employed a company to insulate my three story house in 2011. They started Insulating it in August of 2011...They said it would be a 3-4 day job. They installed it in 0.5"-8" lifts all in the same cavity, this left burned insulation and voids. They removed what they told me was the bad insulation and in the process cut many electrical wires. They fixed this. They then reinstalled too thick again in some spots and removed again. They then installed it for a 3rd time. The areas that I thought were good are now separating from the structural members leaving voids. As of October 2012, 1 year and 2 months of dealing with the contractor I told them I want proof that what has been installed carries a warranty or I want my money back and I will fix the problems myself. They have yet to provide me with this warranty. I have spent many hours in the house looking at what is bad and they need to fix. I am frustrated, 14 months of additional rent due to their negligence. I would like to know how I can get proof that the product carries the manufacturers lifetime warranty, or has it been installed improperly throughout the entire house. Desperately awaiting your response. 
Spray foam is a very specialized packing material, often required for use in shipping valuable fragile items. Engineered packaging principles are designed to protect sculptures, vases, large fossils, lamp bases, busts, computers, furniture, chandeliers and other objects of unusual shape. By virtue of the liquid foam expanding by up to 30-60 times the volume of its liquid state, it efficiently protects almost any size, form and weight. http://www.youtube.com/watch?feature=youtube.be&v=ggLAUsiuI_o
I recently did a remodel project for my basement using spray foam insulation. The original builder has used fiberglass, but I wanted the best insulation i could find. We chose closed cell foam because it blocks moisture from getting into the house. It took one day to install and was fumey for about 3 hours. It was pretty cool watching it being done. It comes out as a liquid and then expands rapidly into a foam. It's quick! Then they took a types of saw to shave it flat with the wall studs so we could then go ahead and drywall.

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