If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
I've seen this only once, and it was with closed cell foam, but I've heard of it happening with open cell foam, too. I don't know the details, but I've heard it could result from a bad batch of chemicals, improper mixing, or too high a temperature. Whatever the cause, it's not a good thing. The photo below shows how the spray foam pulled away from the studs. A little bit of uninsulated area like that adds up to a lot of heat loss/gain when the whole house has that problem, as it did here.
Roof coatings are easy to install. Smaller roofs in good, serviceable condition can be a weekend do-it-yourself (DIY) project. Larger roofs with leaks and ponding water issues should be coated by a qualified professional. Additional roof coating products, such as foam or coatings designed for seams, may be required underneath the main coating layers. Supplement coating products are used to reinforce damaged or leak-prone problem areas.[3]
The video below is from a house near Charleston, South Carolina that I visited recently, and you'll see that the homeowner in this case didn't get his money's worth. I knew immediately when I walked into the attic that something was wrong because it was hot up there. In a properly insulated spray foam attic, the temperature won't be much higher than the house temperature. 
Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include: http://www.youtube.com/v/ggLAUsiuI_o&feature=youtube_gdata
I have used the Froth-Pak 200 to air-seal rim joists--the area above the foundation wall in a basement. The first time I used it I did not shake the canisters well enough and the foam did not cure properly. Don't just shake the box for a few seconds. I take the tanks out of the box so I can shake/invert each tank for a minute or two. You will be able to hear the chemical sloshing around in the tanks. Also, don't ignore the recommended temperature for application--around 75 degrees F. http://youtube.com/watch?feature=youtu.be&v=ggLAUsiuI_o
These coatings are emulsified asphalt and consist of asphalt particles dispersed in water; they utilize clay as the emulsifying component. These coatings also contain many types of organic and/or inorganic fibers and fillers to provide extra strength to the coating. These coatings are available in black, brown, or as a reflective coating when titanium dioxide or aluminum pigments are added.
RetroFoam of Michigan has more than 15 years of experience insulating thousands of homes and pole barns across the lower peninsula. We hear a lot of misconceptions about foam insulation and work to make sure we clear up any wrong ideas about foam insulation. Our staff helped us put together this list of misconceptions adding their insights to dispel any misinformation.
Before you decide on spray foam or another method of insulation, it's important to understand the superiority of spray foam compared to traditional materials. When compared to fiberglass batts, spray foam offers nearly double the R-value per inch, achieves air-sealing and insulation in one step, won't be damaged by mold or moisture, and won't settle, compress, or otherwise be damaged to the point it needs replacement. 

Where Can I Buy Spray Foam Insulation

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