If you cut the nails holding one of the corner studs to the bottom plate and the top plate with a Sawzall, you can use a flat bar (or a flat bar plus a wrecking bar) to pull the stud off the sheathing nails. Either re-use the stud, or buy a new stud, and install the stud with toenails as shown in the link I provided in Comment #51 (this link: Outside corner detail).
As this example illustrates, it's important to seal the envelope completely. One of spray foam's biggest selling points is its air-sealing ability, but it can't seal places where it's not sprayed. One of the nice things about using spray foam in new construction is that you can do a Blower Door test before the drywall goes in. Even better, you can test for leaks with a fog machine. https://youtube.com/v/ggLAUsiuI_o
In general, cantilevered steel beams are a nightmare. If part of the steel beam is in contact with exterior temperatures, then it's best if the interior portion of the steel beam is covered on all sides with insulation. This is generally impossible (because the interior portion of the cantilevered beam generally supports a load, meaning that you can't wrap the steel beam in insulation on all sides).
How Much Is Spray Foam
The Canadian National Building Code references the CAN/ULC S705.2 National Application Standard which must be followed during all installations of 2lb medium density closed cell polyurethane foam. Every installer of CAN/ULC-S705.1 compliant medium density, spray applied foam must be licensed in order to spray foam and hold valid photo ID issued by their Quality Assurance Program (QAP) provider showing their license is in good standing.