The United States has adapted to using sprayfoam insulation and a new technology called Wall Injection to retrofit existing wall construction by drilling small holes between wall studs in the structures framing and filling the void with a less aggressive expanding water based foam. This allows existing home and business owners to conserve energy by creating a thermal envelope in their existing structure.
Today’s “third generation” of blowing agents have a GWP of 700 to 1000 which is still remarkably high considering water/CO2 has a GWP of 1. However, innovation from some chemical manufacturers like the Chemours Company have introduced the next generation of HFO blowing agents such as Opteon 1100, which significantly reduces the GWP impact when using closed-cell spray foam insulation products.
One of the high-tech insulation products being utilized these days is a foam-spray product called "Icynene," which is a foam that starts as two liquid components (a and b, if you will) that are heated up and sent through two hoses and meet at a tip of a gun where the magic begins. This is a thin film that expands to 100 times its volume in eight seconds, when it's permanently set up.

Spray Foam Sealant

Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include:

Where Can I Buy Closed Cell Spray Foam

Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 
FROTH-PAK Foam Sealant is a two-component quick-cure polyurethane FROTH-PAK Foam Sealant is a two-component quick-cure polyurethane foam that fills cavities penetrations cracks and expansion joints. FROTH-PAK foam sealant can also be used as a sealant and void fill in many roofing applications. FROTH-PAK is chemically cured foam which significantly reduces curing time. FROTH-PAK dispenses expands and becomes tack ...  More + Product Details Close

Spray Foam Basement Walls Cost

Closed-cell (aka two-pound foam) is denser than open-cell at about 2 pounds per cubic foot. Its R-Value is between 6-6.5 per inch. As a result, this kind of foam is much more expensive than its counterpart. The reason closed-cell doesn't need a vapor retarder is because it already has one. It's permeance is 0.8 perm, which means it can handle cold climates without the use of an additional board or drywall. Closed-cell uses hydroflurocarbons (HFCs) as part of its makeup. However, this material has been known to have a high global warming effect. If you want a green insulation solution, this is not the material to use. A way to avoid this and still use closed-cell is by installing it alongside fiberglass batts.
This coating is also efficient with a coverage area reaching between 42 and 46 feet. And regardless of the weather, you can apply and use it in your roof to achieve the protection for it you need. Just as what you can read in RV rubber roof coating reviews, this product can work in all temperatures. Regardless it is hot or cold outside, you can easily apply and ensure of its adhesion on your recreational vehicle roof.
Closed-cell foam has a higher density and offers a higher R-value per inch. It also adds strength to walls, ceilings and roofs and can contribute to a structure’s overall durability. Additionally, closed-cell foam’s low water vapor permeability offers protection from moisture when installed in places where high humidity—from climate, occupants, or flooding—meets the structure. 
I employed a company to insulate my three story house in 2011. They started Insulating it in August of 2011...They said it would be a 3-4 day job. They installed it in 0.5"-8" lifts all in the same cavity, this left burned insulation and voids. They removed what they told me was the bad insulation and in the process cut many electrical wires. They fixed this. They then reinstalled too thick again in some spots and removed again. They then installed it for a 3rd time. The areas that I thought were good are now separating from the structural members leaving voids. As of October 2012, 1 year and 2 months of dealing with the contractor I told them I want proof that what has been installed carries a warranty or I want my money back and I will fix the problems myself. They have yet to provide me with this warranty. I have spent many hours in the house looking at what is bad and they need to fix. I am frustrated, 14 months of additional rent due to their negligence. I would like to know how I can get proof that the product carries the manufacturers lifetime warranty, or has it been installed improperly throughout the entire house. Desperately awaiting your response. 
Sealection 500 is a spray-applied adhesive, which once applied, expands in place using water-blown technology, without CFCs, HCFCs, or ozone-depleting chemicals. Unlike traditional fiberglass insulation, Sealection 500 will maintain its performance; time and temperature have no effect on the spray foam insulation's R-value of 3.81 at 1 inch. Sealection 500 never deteriorates or decomposes. The product retains its shape and half-pound density over time, and never settles or compacts.
I've seen this only once, and it was with closed cell foam, but I've heard of it happening with open cell foam, too. I don't know the details, but I've heard it could result from a bad batch of chemicals, improper mixing, or too high a temperature. Whatever the cause, it's not a good thing. The photo below shows how the spray foam pulled away from the studs. A little bit of uninsulated area like that adds up to a lot of heat loss/gain when the whole house has that problem, as it did here.

How Much To Spray Foam Basement